We examine the impact of corporate ownership structure on the value of excess cash in Chinese listed firms. We find that the value of excess cash is less in firms controlled by private investors than in those firms controlled by the government. One dollar of excess cash is valued a $0.36 in firms controlled by private investors while it rises to $0.42 in firms controlled by the government. Furthermore, we show that the expropriation of the controlling shareholders is significantly and positively related with the previous year’s excess cash in firms controlled by private investors while it is insignificant in firms controlled by the government. These findings are consistent with the view that private controlling shareholders have the greater ability to extract private benefit in cash holdings.