This work models the spillover of liquidity and volatility and their joint dynamics in the Chinese stock market. Methodologically, we implement a copula-based vector multiplicative error model for sectors. Utilizing intraday data from 2014 to 2022, our empirical analysis reveals strong interdependence between liquidity and volatility at the sectoral level. Moreover, different sectors dominate the transmission of liquidity and volatility shocks at different times. In normal times, sector volatilities transmit shocks notably (though not always dominantly), while in turbulent times, illiquidity is the key channel through which shocks spread. We also pay special attention to how two catastrophic events impacted the Chinese stock market: the 2015/16 stock market crash and the COVID-19 pandemic. Our ffndings are useful for policymakers monitoring and making policy at the sectoral level, as well as for institutional and private investors making investment decisions.