This study examines the role of financial derivatives in managing operational and financial risks within China's chemical manufacturing sector. While prior research has primarily focused on financial determinants of hedging decisions, we highlight the significant influence of operational metrics—particularly inventory levels and turnover rates—in shaping firms’ engagement in derivatives markets. Drawing from a sample of 289 publicly listed chemical firms from 2016 to 2022, we employ probit regression and K-means clustering to explore how operational and financial factors jointly determine derivatives adoption. Our empirical results reveal that operational metrics have a non-negligible impact on hedging decisions. Specifically, inventory and turnover rates emerge as primary determinants of firms' initiatives, while pre-tax operating profit remains significant from a financial perspective. The moderation analysis of cash flow reveals that financially constrained firms prioritize derivatives for operational risk mitigation, while resource-abundant firms employ them selectively for strategic optimization. Furthermore, our robustness tests, which control for geographical distinctions and the COVID-19 effect, confirm that firm-specific operational characteristics consistently dominate firms' hedging decisions despite regional heterogeneity. Finally, clustering analysis underscores the interplay between operational efficiency and capital robustness, showing that firms exhibiting superior operational efficiency and capital robustness demonstrate higher engagement in derivatives hedging. These findings contribute to the corporate risk management literature by expounding on the primacy of operational considerations in derivatives usage, particularly in asset-intensive industries. The study also provides practical implications for manufacturing firms navigating volatile market conditions, emphasizing that integrating operational and financial strategies is crucial for effective risk management.